7.46 The ionization constant of acetic acid is 1.74 × 10–5. Calculate the degree of dissociation of acetic acid in its 0.05 M solution. Calculate the concentration of acetate ion in the solution and its pH.

Method 1

 

1.    CH3COOH↔CH3COO-+H+  Ka=1.74×10-5
2.    H2O+H2O↔H3O++OH-       Kw=1.0×10-14
Since Ka>>Kw :
        CH3COOH+H2O↔CH3COO-+H3O+
Ci=0.05                                 0                   0
        0.05α-0.5α                 0.05α           0.05α
Ka=.05α0.5α0.5-0.05α
     =.05α0.05α0.51-α
     =0.5α21-α
1.74×10−5=0.05α21−α1.74×10−5−1.74×10−5α=0.05α20.05α2+1.74×10−5α−1.74×10−5D=b2−4ac=(1.74×10−5)2−4(.05)(1.74×10−5)=3.02×10−25+.348×10−5α=Kacα=1.74×10−5.05=34.8×10−5×1010=3.48×10−6
=CH3COOH↔CH3COO-+H+

 

α1.86×10-3CH3COO-=0.05×1.86×10-3                      =0.93×10-31000                       =.000093Method 2Degree of dissociation,α=Kacc=0.05 MKa=1.74×10-5Then,  α=1.74×10−5.05α=34.8×10−5α=3.48×10−4α=1.8610−2CH3COOH↔CH3COO-+H+Thus, concentration of CH3COO-=c=.05×1.86×10-2=.093×10-2=.00093 Since OAc-=H+,H+=.00093=.093×10-2.pH=-logH+      = -log.093×-10-2∴pH=3.03

Hence, the concentration of acetate ion in the solution is 0.00093 M and is PH is 3.03.