Consider the following rate expression.
The order of reaction and dimension of the rate constant are, respectively-
1. ; k =
2. 3; k =
3. ; k =
4. ; k =
What are the dimensions of the rate constant K in the rate law \(\text { Rate }=k\left[H_2 O_2\right]\left[I^{-}\right]\)?
| 1. | 2. | ||
| 3. | 4. |
For the reaction 2A + B → A₂B, the rate law is rate = k[A][B]², where k = 2.0 × 10⁻⁶ mol⁻² L² s⁻¹,
[A] = 0.1 M, and [B] = 0.2 M. What is the initial rate of the reaction?
1. 0.04 mol
2. 8
3. 8
4. 8 mol
The decomposition of NH3 on a platinum surface is a zero-order reaction. The rates of production of N2 and H2 will be respectively:
(given ; k = 2.5 × 10–4 mol–1 L s–1 )
| 1. | 2.5 × 10−4 mol L−1 s−1 and 5.5 × 10−4 mol L−1 s−1
|
| 2. | 2.5 × 10−4 mol L−1 s−1 and 7.5 × 10−4 mol L−1 s−1
|
| 3. | 1.5 × 10−4 mol L−1 s−1 and 4.5 × 10−4 mol L−1 s−1
|
| 4. | 0.5 × 10−4 mol L−1 s−1 and 3.5 × 10−4 mol L−1 s−1 |
The rate equation of a reaction is expressed as, Rate = \(k(P_{CH_{3}OCH_{3}})^{\frac{3}{2}}\)
(Unit of rate = bar min–1)
The units of the rate constant will be:
1. bar1/2 min
2. bar2 min–1
3. bar–1 min–2
4. bar–1/2 min–1
The factor(s) that affect the rate of a chemical reaction is/are:
| 1. | Concentration/Pressure of reactants. |
| 2. | Temperature. |
| 3. | Presence of a catalyst. |
| 4. | All of the above. |
If the concentration of the reactant is made twice, the new rate of reaction for the second order reaction would be-
1. 2 times
2. 4 times
3. 3 times
4. No change in the rate of the reaction
Which of the following statements regarding the rate constant of a reaction is correct?
| 1. | The rate constant approximately doubles with an increase in temperature of 10 °C |
| 2. | The rate constant becomes half with an increase in temperature of 10 °C |
| 3. | The rate constant remains unchanged with a rise in temperature by 10 °C |
| 4. | None of the above |
| t/s | 0 | 30 | 60 | 90 |
| [Ester]/mol L–1 | 0.55 | 0.31 | 0.17 | 0.085 |
A reaction is first-order with respect to A and second-order with respect to B. The concentration of B is increased three times. The new rate of the reaction would:
| 1. | Decrease 9 times | 2. | Increase 9 times |
| 3. | Increase 6 times | 4. | Decrease 6 times |