A cell is given as 
\(\mathrm{M}(\mathrm{~s})\left|\mathrm{M}^{\mathrm{n}+}(\mathrm{aq}) \| \mathrm{M}^{+\mathrm{n}}(\mathrm{aq})\right| \mathrm{M}(\mathrm{~s})\)
For which of the following condition, \(E_{cell}\) is positive:
1. \(C_1 < C_2\) (If \(C_1\) is concentration at cathode)
2. \(C_2 < C_1\) (If \(C_1\) is concentration at anode)
3. \(C_1 < C_2\) (If \(C_2 \) is concentration at anode)
4. \(C_1 > C_2\) (If \(C_1\) is concentration at cathode)
Subtopic:  Electrolytic & Electrochemical Cell |
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Level 2: 60%+
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Find out \(\mathrm{E}_{\text {cell }}^{\circ}\) of the given cell:

\(\begin{aligned} & \mathrm{M}\left|\mathrm{M}^{2+} \| \mathrm{X}^{2-}\right| \mathrm{X} \\ & \mathrm{E}_{\mathrm{M}^{2+} \mid \mathrm{M}}^{\circ}=0.34 \mathrm{~V} \\ & \mathrm{E}_{\mathrm{X} \mid \mathrm{X}^{2-}}^{\circ}=0.46 \mathrm{~V} \end{aligned}\)

1. \(0.80 \mathrm{~V}\)
2. \(0.12 \mathrm{~V}\)
3. \(-0.12 \mathrm{~V}\)
4. \(-0.80 \mathrm{~V}\)
Subtopic:  Electrolytic & Electrochemical Cell |
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How many of the given statements are true for a fuel cell?
(a) It is a type of Galvanic cell.
(b) It is used for providing electrical power in space programs.
(c) Hydrogen and oxygen are bubbled through porous carbon electrodes into concentrated \(NaOH ~\)solution.
(d) It produces electricity with an efficiency of \(40\%\)
(e) It is a pollution-free cell.
1. (a), (b), (c), and (e) 
2. (a), (b), and (e) 
3. (a), (c), (d), and (e) 
4. (a), (b), (d), and (e)
Subtopic:  Electrolytic & Electrochemical Cell |
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Match the two lists and choose the correct option:
List-I List-II
(i)  Ni-Cd cell  (a)  Rechargeable
(ii)  Fuel cell (b)  Anode \(\left(\mathrm{Zn} \rightarrow \mathrm{Zn}^{2+}+2 \mathrm{e}^{-}\right)\)
(iii)  Mercury cell (c)  Used in hearing aid
(iv)  Leclanché cell  (d)  Converts combustion energy into electrical energy

1. (i)-(a); (ii)-(d); (iii)-(c), (iv)-(b)
2. (i)-(b); (ii)-(a); (iii)-(c), (iv)-(d)
3. (i)-(d); (ii)-(a); (iii)-(c), (iv)-(b)
4. (i)-(a); (ii)-(b); (iii)-(c), (iv)-(d)
Subtopic:  Electrolytic & Electrochemical Cell |
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Level 1: 80%+
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The \(\left(\frac{\partial \mathrm{E}}{\partial \mathrm{T}}\right)_P \) of different types of half cells are as follows:
\(\begin{array}{cccc} \text { A } & \text { B } & \text { C } & \text { D } \\ 1 \times 10^{-4} & 2 \times 10^{-4} & 0.1 \times 10^{-4} & 0.2 \times 10^{-4} \end{array}\)
(Where E is the electromotive force)
Which of the above half cells would be preferred to be used as reference electrode?

1. A
2. B
3. C
4. D
Subtopic:  Electrolytic & Electrochemical Cell |
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Level 2: 60%+
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What is the value of \(E^o_{cell}\) for the cell given below?
\(Ag|Ag^+ || Cu^{2+}|Cu\)
 

\(Given :\begin{aligned} \mathrm{Ag}^{+}+\mathrm{e}^{-} \longrightarrow \mathrm{Ag},~ & E^{\circ}=x \\ \mathrm{Cu}^{2+}+2 e^{-} \longrightarrow \mathrm{Cu}, ~& E^{\circ}=y \end{aligned}\)

1. x + 2y 2. 2x + y
3. y-x 4. y - 2x
Subtopic:  Electrolytic & Electrochemical Cell |
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Level 2: 60%+
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