The compound \(CH_3-CH_2-CH(Cl)-CH_3\) obtained by chlorination of n-butane is an example of :
1. Meso form
2. Racemic mixture
3. d-form
4. l-form
An organic compound A, having molecular formula C₄H₉Cl, reacts with sodium in dry diethyl ether to give a hydrocarbon.
This hydrocarbon on monochlorination gives only one chloro derivative.
Identify compound A.
1. t-Butyl chloride
2. sec. Butyl chloride
3. Iso butyl chloride
4. n-Butyl chloride
The reactivity order of halides for dehydrohalogenation is:
1. R–F > R–Cl > R–Br > R–I
2. R–I > R–Br > R–Cl > R–F
3. R–I > R–Cl > R–Br > R–F
4. R–F > R–I > R–Br > R–Cl
Given below is a reaction sequence:
\(\begin{aligned} & CH_3CH_2Cl\xrightarrow{NaCN}X\xrightarrow{H_2/Ni}Y\\ &Y\xrightarrow{\text{Acetic Anhydride}}Z \end{aligned}\)
Z in the above reaction is:
1. CH3CH2CH2NHCOCH3
2. CH3CH2CH2NH2
3. CH3CH2CH2CONHCH3
4. CH3CH2CH2CONHCOCH3
\(CH_3CH_2CHCl_2\) upon reaction with \(NaNH_2\) gives:
| 1. | 2. | ||
| 3. | 4. |
The –OH group of an alcohol or the carboxylic acid can be replaced by – Cl using:
| 1. | Hypochlorous acid | 2. | Chlorine |
| 3. | Hydrochloric acid | 4. | Phosphorous pentachloride |
Chloropicrin is obtained by the reaction of:
1. Nitric acid on chlorobenzene.
2. Chlorine on picric acid.
3. Nitric acid on chloroform.
4. Steam on carbon tetrachloride.
Which of the following undergoes nucleophilic substitution exclusively by SN1 mechanism?
1. Ethyl chloride
2. Isopropyl chloride
3. Benzyl chloride
4. Chlorobenzene