If partial pressure of oxygen is 0.5 atm and KH = 1.4 × 10-3 M/atm, then the amount of oxygen dissolved in 100 ml water at 298K is-
| 1. | 22.4 mg | 2. | 22.4 g |
| 3. | 2.24 g | 4. | 2.24 mg |
The vapour pressure of pure benzene and toluene are 160 and 60 torr respectively. The mole fraction of toluene in vapour phase in contact with an equimolar solution of benzene and toluene is -
| 1. | 0.50 | 2. | 0.6 |
| 3. | 0.27 | 4. | 0.73 |
The Henry's law constant for the solubility of N2 gas in water at 298 K is 1.0 × 105 atm. The mole fraction of N2 in air is 0.8. The number of moles of N2 formed from air dissolved in 10 moles of water at 298 K and 5 atm pressure is-
| 1. | 4.0 × 10–4 mol | 2. | 4.0 × 10–5 mol |
| 3. | 5.0 × 10–4 mol | 4. | 4.0 × 10–6 mol |
A 500 g toothpaste sample has 0.4 g fluoride concentration. The fluoride concentration in terms of ppm will be -
| 1. | 200 ppm | 2. | 400 ppm |
| 3. | 500 ppm | 4. | 800 ppm |
An aqueous solution of hydrochloric acid -
1. Obeys Raoult's law
2. Shows negative deviations from Raoult's law
3. Shows positive deviations from Raoult's law
4. Obeys Henry's law at all compositions
Total vapour pressure of mixture of 1 mol X and 2 mol Y is 240 torr. In this case -
| 1. | There is a negative deviation from Raoult's law |
| 2. | There is a positive deviation from Raoult's law |
| 3. | There is no deviation from Raoult's law |
| 4. | Can not be decided |
The azeotropic mixture of water and ethanol boils at 78.15 oC. When this mixture is distilled, it is possible to obtain-
1. Pure H2O
2. Pure C2H5OH
3. Pure H2O as well as pure C2HOH
4. Neither H2O nor C2H5OH in their pure state
The feeling of weakness and discomfort in breathing at high altitudes is based on-
| 1. | Boyle's law | 2. | Charles's law |
| 3. | Henry's law | 4. | Raoult's law |
The maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon:
| 1. | Temperature | 2. | Nature of solute |
| 3. | Pressure | 4. | Nature of solvent |
4 L of 0.02 M aqueous solution of NaCl was diluted by adding 1 L of water. The molarity of the resultant solution is:
| 1. | 0.004 M | 2. | 0.008 M |
| 3. | 0.012 M | 4. | 0.016 M |
The positive deviations from Raoult’s law mean the vapour pressure is:
1. Higher than expected.
2. Lower than expected.
3. As expected.
4. None of the above
If 22 g of benzene is dissolved in 122 g of CCl4, the mass percentage of CCl4 and benzene respectively are-
1.
2.
3.
4. 91.28 %, 8.72 %
Match the following type of intermolecular interactions present in the pair of compounds given:
| (a) | Methanol and Acetone | (i) | Van der Waal’s forces of attraction |
| (b) | Acetonitrile and Acetone | (ii) | Ion-dipole interaction |
| (iii) | Dipole-dipole interaction |
| (a) | (b) | |
| 1. | (iii) | (ii) |
| 2. | (ii) | (ii) |
| 3. | (iii) | (iii) |
| 4. | (iii) | (i) |
What mass of urea is needed to prepare 2.5 kg of a 0.25 m aqueous solution?
| 1. | 73 g | 2. | 37 g |
| 3. | 48 g | 4. | 24 g |
The solubility of \(H_2S\) in water at STP is 0.195 m. The value of Henry's constant is:
| 1. | 274 atm | 2. | 285 atm |
| 3. | 295 atm | 4. | 278 atm |
The solubility of gases in liquids generally decreases as temperature increases.
The primary reason for this behavior is:
| 1. | Dissolution of a gas in a liquid is an endothermic process. |
| 2. | Dissolution of a gas in a liquid is an exothermic process. |
| 3. | Gases are highly compressible. |
| 4. |
All of the above statements are correct. |
| Type of solution | Example | ||
| a. | Solid in gas | i. | Aerated water |
| b. | Gas in liquid | ii. | Smoke |
| c. | Liquid in solid | iii. | Solution of hydrogen in palladium |
| d. | Gas in solid | iv. | Amalgams |
| a | b | c | d | |
| 1. | i | iii | iv | ii |
| 2. | ii | i | iv | iii |
| 3. | iii | i | iv | ii |
| 4. | iv | i | ii | iii |
The density of 68 % nitric acid by mass in an aqueous solution is 1.504 g mL–1. The molarity of the acid solution would be:
1. 15.24 M
2. 16.23 M
3. 14.52 M
4. 13.45 M
A solution is obtained by mixing 300 g of 25 % solution and 400 g of 40 % solution by mass. The mass percentage of solute in the resulting solution is:
1. 33.5 %
2. 36.5 %
3. 37.4 %
4. 32.5 %