In the reaction,

${\mathrm{CH}}_3\mathrm{CN}+2\mathrm{H}\underset{{\mathrm{SnCl}}_2}{\overset{\mathrm{HCl}}{\to }}X<mspace\; width="1em"></mspace>\stackrel{\mathrm{Boiling}<mspace\; width="1em"></mspace>{\mathrm{H}}_2\mathrm{O}}{\to }<mspace\; width="1em"></mspace>Y,$ the term Y is 

[1999]

1. Acetone

2. Ethanamine

3. Acetaldehyde

4. Dimethyl amine

RMgX on reacting with cyanogen chloride gives:

1. R-NC

2. R-Cl

3. R-CN

4. None of the above

X and Y in the given reaction are:

1. ${\mathrm{CH}}_3\mathrm{COOH}<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>({\mathrm{CH}}_3{)}_2\mathrm{NH}$

2. ${\mathrm{CH}}_3{\mathrm{CONH}}_2<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>{\mathrm{CH}}_3\mathrm{OH}$

3. ${\mathrm{CH}}_3\mathrm{CHO}<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>({\mathrm{CH}}_3{)}_2\mathrm{NH}$

4. ${\mathrm{CH}}_3{\mathrm{COCH}}_3<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>{\mathrm{CH}}_3{\mathrm{NH}}_2$

Which of the following is the strongest base ?
 

1.
2.
3.
4.

1.  

2. 

3. 

4. 

Primary, secondary and tertiary nitroalkanes can be identifier by the action of:

1. ${\mathrm{HNO}}_2<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>\mathrm{NaOH}\left(aq\right)$

2. ${\mathrm{CHCl}}_3<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>\mathrm{NaOH}<mspace\; width="1em"></mspace>\left(aq\right)$

3. ${\mathrm{CHCl}}_3<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>\mathrm{KOH}(\mathrm{alc}.)$

4. none of these

Consider the following sequence of reactions

Compound[A]$\stackrel{\mathrm{Reduction}}{\to }$[B] $\stackrel{{\mathrm{HNO}}_2}{\to }{\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{OH}$ 

The compound [A] is

1. CH₃CH₂CN

2. CH₃NO₂

3. CH₃NC

4. CH₃CN

Which of the following statements about primary amines is false ?

[2010]

1. Alkyl amines are stronger bases than aryl amines

2. Alkyl amines react with nitrous acid to produce alcohols

3. Aryl amines react with nitrous acid to produce phenols

4. Alkyl amines are stronger bases than ammonia

When NaNO₂ and dilute HCl were added to an amine at $0°\mathrm{c}$, a colourless gas was evolved and an ionic compound is formed. The amine is:

1. any primary amine

2. an aromatic primary amine

3. any amine

4. none of the above

The compound obtained by heating a mixture of primary amine and chloroform with ethanolic potassium hydroxide (KOH) is

[1997]

1. An alkyl isocyanide

2. An alkyl halide

3. An amide

4. An amide and nitro compound

Identify 'Z' in the change;

${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NH}}_2\underset{280\mathrm{K}}{\overset{{\mathrm{NaNO}}_2/\mathrm{HCl}}{\to }}\mathrm{X}\stackrel{\mathrm{CuBr}/\mathrm{HBr}}{\to }\mathrm{Z}:$




 

1.
2.
3.
4.

1.  

2. 

3. 

4.